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Benjamin Silliman (August 8, 1779 – November 24, 1864) was an eminent American chemist, science educator, and early pioneer in the development of the petroleum industry. 

Educated at Yale, Silliman received his B.A. in 1796 and M.A. in 1799, later becoming one of the first American professors of science at Yale. In 1802, he was appointed by Yale President Timothy Dwight IV as a professor of chemistry and natural history, despite his initial lack of expertise in chemistry. This appointment marked the beginning of a distinguished career, during which Silliman introduced the process of fractional distillation to America and significantly advanced the scientific understanding of geology and mineralogy.

In 1818, Silliman founded the American Journal of Science, the oldest continuously published scientific journal in the United States. His work on this publication and his various scientific inquiries, such as the analysis of the Weston meteorite in 1807, underscored his role as an influential disseminator of scientific knowledge. His identification of several minerals and his involvement in the early documentation of fossil fishes in the U.S. further highlight his broad impact on natural sciences.

Silliman's connection to the petroleum industry began with his analysis of rock oil samples from Pennsylvania in the mid-19th century. His favorable report on these samples anticipated the economic and industrial potential of petroleum, thereby facilitating the early development of the oil industry in America. Despite later controversies involving allegations of sample tampering during his consultancy in California, Silliman's initial insights contributed significantly to the burgeoning field of petroleum exploration and extraction.

An advocate for education, Silliman supported coeducation at Yale, allowing women to attend his lectures long before their formal admission to the university. His legacy in education is complemented by his personal life, where he raised a family deeply embedded in the academic and scientific communities. His first marriage to Harriet Trumbull linked him to prominent Connecticut figures, and his children and their spouses continued his tradition of scientific inquiry.

Silliman's influence extended beyond his immediate scientific contributions. He was a vocal advocate for old Earth creationism, engaging in public debates about the reconciliation of geological discoveries with biblical texts. His views on religion and science reflected the complex dialogues of his time.

Benjamin Silliman's legacy continues through various commemorations, including Yale's Silliman College and the mineral sillimanite named in his honor. His foundational role in American science and education, coupled with his visionary engagement with the petroleum industry, cements his status as a significant figure in the annals of American history.